Suyuan Chemical
Знание

Material Safety Data Sheet (MSDS) – Tetradecyl Primary Amine

Identification

Product Name: Tetradecyl Primary Amine
Chemical Formula: C14H31NH2
CAS Number: 2016-42-4
Synonyms: 1-Tetradecylamine, Myristylamine
Product Use: Used as intermediate in chemicals, surfactants, flotation agents, corrosion inhibitors
Supplier/Manufacturer: Contact details from distributor or direct source
Emergency Phone Number: Reference company-specific emergency contact provided on label or SDS

Hazard Identification

Classification: Harmful if swallowed, Causes skin and eye irritation, May cause respiratory irritation
GHS Label Elements: Signal Word: Warning
Hazard Statements: H315: Causes skin irritation, H319: Causes serious eye irritation, H302: Harmful if swallowed
Pictograms: Exclamation mark for irritant effects
Precautionary Statements: Do not breathe dust, Wash skin after handling, Wear protective gloves and eye protection, Avoid release to the environment
PPE Symbols: Gloves, goggles

Composition / Information on Ingredients

Chemical Name: Tetradecyl Primary Amine
Common Name: Myristylamine
Concentration: ≥98% by weight
CAS Number: 2016-42-4
Impurities: Trace secondary and tertiary amines, saturated hydrocarbons
Additives: None commonly added, confirm with specific supplier’s batch analysis

First Aid Measures

Inhalation: Move to fresh air, seek medical advice if symptoms like coughing or dizziness develop
Skin Contact: Immediately remove contaminated clothing, wash with soap and water, seek medical advice if irritation continues
Eye Contact: Rinse for at least 15 minutes with water, hold eyelids apart, seek medical attention fast if symptoms like redness persist
Ingestion: Rinse mouth, do not induce vomiting, seek immediate medical advice, show label or SDS to medical personnel
Most Important Symptoms: Irritation, burning sensation on skin, eye watering, gastrointestinal upset if ingested
Note to Physician: Symptomatic treatment, consult poison center for more details

Fire-Fighting Measures

Suitable Extinguishing Media: Dry chemical powder, CO2, foam, do not use strong water jets
Special Hazards: May emit toxic or irritating fumes (nitrogen oxides, hydrocarbons) at high temperature
Fire Fighting Instructions: Fully encapsulate with self-contained breathing apparatus, protective clothing, avoid inhalation of fumes
Explosion Data: Not highly explosive, avoid dust accumulation
Additional Advice: Remove containers from fire area if possible, use water spray to cool exposed surfaces

Accidental Release Measures

Personal Precautions: Avoid contact with skin, eyes and clothing, ventilate area, wear appropriate protective equipment (goggles, gloves, overalls)
Environmental Precautions: Prevent spillage from entering drains or waterways, alert authorities if contamination occurs
Cleanup Methods: Collect with inert absorbent (e.g., sand), scoop into approved waste container, wash area with soap and water, dispose as hazardous waste according to regulations
Spill Response: Isolate leak, use non-sparking tools, store in labeled container for disposal

Handling and Storage

Handling: Use in well-ventilated areas, avoid inhalation and direct contact, use local exhaust, wash hands before eating or smoking
Storage Conditions: Store in tightly closed original container, away from moisture, acids, oxidizers, and direct sunlight
Storage Temperature: Room temperature recommended, avoid freezing and high heat
Incompatible Materials: Strong acids, oxidizing agents, halogens
Other Precautions: Keep away from food and beverages, label storage area clearly

Exposure Controls and Personal Protection

Exposure Limits: No specific occupational exposure limits established by OSHA, ACGIH, or NIOSH (always check latest updates)
Engineering Controls: Use process enclosures, local exhaust, or other engineering controls to keep airborne levels below recommended exposure
Personal Protection Equipment: Protective gloves (nitrile, neoprene), chemical splash goggles, long-sleeved clothing, protective footwear
Respiratory Protection: Use proper NIOSH-approved respirator for dusty or poorly-ventilated settings
Hygiene Measures: Do not eat, drink, or smoke while handling, wash thoroughly after handling

Physical and Chemical Properties

Appearance: White to yellowish solid (flakes or pellets)
Odor: Amine-like, strong
Melting Point: 45–49°C
Boiling Point: 288°C
Solubility: Insoluble in water, soluble in alcohol, chloroform, ether
Vapor Pressure: Very low at room temperature
Specific Gravity: 0.78–0.81 (at 20°C)
pH: Not applicable for solid form
Other Properties: Non-volatile, stable under recommended storage, forms corrosive salts with acids

Stability and Reactivity

Chemical Stability: Stable under standard use and storage conditions
Conditions to Avoid: Store away from heat, open flames, and sources of ignition
Reactivity: May react with oxidizing agents, acids, halogenated compounds
Hazardous Decomposition Products: Nitrogen oxides, carbon oxides, ammonia fumes when exposed to high heat or flames
Polymerization: No hazardous polymerization expected

Toxicological Information

Routes of Exposure: Skin contact, eye contact, ingestion, inhalation
Acute Toxicity: LD50 (oral, rat): 600–1,000 mg/kg
Skin Effects: Causes irritation, possible allergic reaction in sensitive persons
Eye Effects: Causes severe irritation, risk of corneal injury
Inhalation Risks: Dust can irritate mucous membranes, nose, and throat
Chronic Effects: Not classified as a carcinogen; long-term exposure data limited
Other Health Hazards: Repeated contact can cause dermatitis; ingestion leads to gastrointestinal upset

Ecological Information

Ecotoxicity: Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment
Persistence and Degradability: Moderately persistent in environment; breaks down slowly in soil and water
Bioaccumulation: Potential for bioaccumulation in aquatic species
Mobility in Soil: Low water solubility decreases mobility; tends to bind to soil particles
Other Environmental Hazards: Careless release can disrupt local water systems

Disposal Considerations

Waste Treatment Methods: Dispose of in accordance with local, regional, and national regulations
Solid Waste Disposal: Send to licensed chemical waste incinerator or approved landfill
Contaminated Packaging: Triple-rinse containers before disposal, do not reuse containers
Other Disposal Instructions: Avoid discharge into drains or natural water bodies

Transport Information

UN Number: 2735 (when classified as a corrosive amine by regulations)
UN Proper Shipping Name: Amines, liquid, corrosive, n.o.s. (contains tetradecylamine), if shipped in a molten form; otherwise, follow local rules
Transport Hazard Class: 8 (Corrosive), assigned if classified under packing/grading rules
Packing Group: III for lower-risk forms
Marine Pollutant: Classified as dangerous for sea transit due to aquatic toxicity
Special Precautions: Keep away from foodstuffs, animal feed, and avoid contact with acids

Regulatory Information

Inventory Status: Listed in TSCA, EINECS, DSL, and other main global inventories
Regulatory Compliance: OSHA Hazardous Chemical, subject to SARA Title III reporting requirements in some locations
Label Requirements: Hazard pictograms, risk phrases, and safety instructions as per local legislation
EPA Regulations: Not considered a hazardous waste under RCRA; local water discharge limits apply
International Restrictions: Review REACH status in EU, consult national resources for country-specific information
Additional Notes: Always review current requirements, as regulatory landscape changes frequently