Suyuan Chemical
Знание

Material Safety Data Sheet: N,N-Diethyl-1,3-Propanediamine

Identification

Product Name: N,N-Diethyl-1,3-Propanediamine
Chemical Formula: C7H18N2
CAS Number: 553-58-0
Synonyms: 1,3-Propanediamine, N,N-diethyl-
Manufacturer: Refer to supplier label for manufacturer identity
Recommended Use: Intermediate in chemical synthesis, corrosion inhibitors, surfactant production
Emergency Contact: Refer to local hazardous materials registry or Poison Control Center for local guidance

Hazard Identification

GHS Classification: Flammable liquid (Category 3), Acute Toxicity Oral (Category 4), Skin Corrosion/Irritation (Category 1)
Label Elements: Flame, Corrosive pictogram, Exclamation mark
Signal Word: Danger
Hazard Statements: Causes severe skin burns and eye damage; may cause respiratory irritation; harmful if swallowed; flammable liquid and vapor
Precautionary Statements: Avoid breathing vapors; wash skin thoroughly after handling; wear protective gloves, clothing, and eye, face protection; keep away from heat, sparks, open flames
Other Hazards: Releases toxic fumes on combustion; vapors heavier than air

Composition / Information on Ingredients

Chemical Name: N,N-Diethyl-1,3-Propanediamine
Content: ≥98%
Impurities or Stabilizing Additives: Less than 2% proprietary or trace components as noted by supplier
CAS Number: 553-58-0
EC Number: 209-054-2

First Aid Measures

Inhalation: Remove person to fresh air; provide oxygen if breathing is difficult; seek medical attention quickly
Skin Contact: Remove contaminated clothing and rinse skin with plenty of water for at least 15 minutes; seek medical help for irritation, burns, or persistent symptoms
Eye Contact: Rinse eyes immediately with flowing water for at least 20 minutes; hold eyelids apart; call emergency services without delay
Ingestion: Rinse mouth, never induce vomiting; do not offer anything by mouth if unconscious; seek urgent medical assessment
Most Important Symptoms: Burning of mucous membranes, redness, swelling, tissue damage, respiratory discomfort
Immediate Medical Attention: Needed for any exposure through eyes, skin burns, breathing difficulty, or accidental ingestion

Fire-Fighting Measures

Suitable Extinguishing Media: Small fires: dry chemical, CO2, or alcohol-resistant foam; large fires: water spray, fog
Specific Hazards: Material gives off toxic and corrosive gases, including nitrogen oxides, carbon monoxide, carbon dioxide
Special Protective Equipment: Full protective gear with self-contained breathing apparatus; avoid inhalation of combustion products
Recommendations: Move containers from fire area if safe to do so, cool with water spray, stay upwind

Accidental Release Measures

Personal Precautions: Wear chemical-resistant gloves, splash goggles, face shield, apron; restrict unprotected access
Environmental Precautions: Prevent further leakage; avoid discharge to drains, watercourses, or soil
Spill Cleanup Methods: Absorb small spills with inert materials (sand, earth); collect in closed, labeled containers for disposal; for large releases, dike for later disposal, ventilate area, and wash spill site after material pickup
Emergency Procedures: Evacuate area, ensure adequate ventilation, dispose contaminated materials according to local regulations

Handling and Storage

Handling: Operate in well-ventilated zones, avoid breathing vapors, do not get on skin, in eyes, or on clothing, use spark-proof tools and explosion-proof electrical equipment
Storage Conditions: Keep container tightly closed in a cool, dry, well-ventilated area; store away from acids, oxidizers, heat sources, and incompatible chemicals
Storage Materials: Only use containers made of compatible material such as HDPE, glass, or stainless steel; avoid copper or aluminum
Special Considerations: Post hazard labels on all storage sites, maintain spill response supplies nearby while handling bulk quantities

Exposure Controls and Personal Protection

Exposure Limits: No established OSHA, ACGIH, or NIOSH exposure limits; handle as hazardous material
Engineering Controls: Use local exhaust ventilation, provide safety showers and eyewash facilities, use closed systems or process enclosures when feasible
Personal Protective Equipment: Splash-resistant goggles, chemical resistant gloves (nitrile, butyl rubber), full-length lab coats; for large volumes or splashing risk, face shield and apron
Respiratory Protection: If ventilation insufficient, wear NIOSH-approved respirator with organic vapor/acid gas cartridges
Hygiene Measures: Wash hands thoroughly after use, do not eat, drink, or smoke while using or storing

Physical and Chemical Properties

Appearance: Clear, colorless to pale yellow liquid
Odor: Ammonia-like, strong fishy scent
pH: Alkaline aqueous solution
Melting Point: -55°C
Boiling Point: 180 – 185°C at 760 mmHg
Flash Point: 63°C (closed cup)
Evaporation Rate: Not determined
Flammability: Flammable liquid
Vapor Pressure: 1.3 mmHg at 25°C
Solubility: Easily soluble in water, ethanol, ether
Specific Gravity: 0.82 – 0.85 (water=1)
Viscosity: Not established
Partition Coefficient (n-octanol/water): No data available

Stability and Reactivity

Chemical Stability: Stable under recommended handling, storage, and usage conditions
Conditions to Avoid: Avoid contact with open flame, hot surfaces, direct heat, direct sunlight
Incompatible Materials: Strong oxidizers, strong acids, acid chlorides, copper, and copper alloys
Hazardous Decomposition Products: Nitrogen oxides, carbon monoxide, carbon dioxide, irritating and toxic fumes
Polymerization: No evidence of hazardous polymerization under normal circumstances

Toxicological Information

Likely Routes of Exposure: Inhalation, skin absorption, ingestion, eye contact
Acute Toxicity (Oral LD50): Rat: 862 mg/kg
Acute Toxicity (Dermal LD50): No data in public sources
Skin Corrosion/Irritation: Causes burns, blisters, prolonged contact can cause deep ulceration
Eye Damage/Irritation: Severe eye irritant, causes possible permanent injury
Respiratory Effects: Vapors cause cough, sore throat, chest tightness; high vapor concentrations can lead to pulmonary edema
Chronic Effects: Prolonged exposure may produce dermatitis, persistent respiratory difficulties
Carcinogenicity: No components listed as potential carcinogens by NTP, IARC, OSHA
Reproductive and Developmental Effects: No reliable data

Ecological Information

Ecotoxicity: Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment
Aquatic Toxicity: No reference data available for EC50 or LC50
Persistence and Degradability: Expected to be biodegradable but rate may vary by conditions
Bioaccumulative Potential: Low, predicted log Kow −0.17
Mobility in Soil: Readily migrates in water, risk of groundwater contamination
Other Adverse Effects: Potential to cause eutrophication if released in bulk into surface waters

Disposal Considerations

Waste Treatment Methods: Dispose through licensed chemical waste contractor, employ incineration or chemical treatment suited for amines
Container Disposal: Rinse containers thoroughly before discarding, remove hazard labels, follow local hazardous waste disposal regulations
Precautions: Avoid release to sewers, surface, or ground water; keep waste and residue separated, do not mix with municipal trash

Transport Information

UN Number: UN2733
Proper Shipping Name: N,N-Diethyl-1,3-propanediamine
Transport Hazard Class: 8 (Corrosive), subsidiary risk: 3 (Flammable Liquid)
Packing Group: II (Medium hazard)
Labels Required: Corrosive, Flammable Liquid
Special Precautions: Secure containers properly, segregate from acids, oxidizers; keep out of direct sunlight, away from food and animal feed transport
Sea/IMDG: EmS F-E, S-C; MARPOL Annex II: Pollution Category X
Air/IATA: Same hazard class and packing group, cargo aircraft only

Regulatory Information

TSCA: Listed on the US Toxic Substances Control Act Inventory
DSL/NDSL (Canada): Listed/Not listed (verify supplier documentation)
REACH (Europe): Subject to registration, check ECHA compliance
OSHA: Classified hazardous per Hazard Communication Standard
SARA Title III (Sections 302, 304, 311/312, 313): Not listed as an Extremely Hazardous Substance or known toxic release inventory chemical
California Proposition 65: Not listed
Other, Local and National Regulations: Consult regional environmental, chemical, and safety regulations for handling, storage, spill, and emission thresholds