Ascent Petrochem Holdings Co., Limited
Знание


Material Safety Data Sheet: Alkyl Ethoxy Polyglycosides (AEG)

Identification

Product Name: Alkyl Ethoxy Polyglycosides
Chemical Family: Nonionic surfactants
SYNONYMS: APGs, Alkyl Polyglucoside, Ethoxylated Alkyl Polyglycoside
CAS Number: 68515-73-1, 110615-47-9 (varies with degree of polymerization and ethoxylation)
Manufacturer: Typical suppliers include industrial chemical producers specializing in surfactants
Recommended Use: Cleaning products, detergents, shampoos, personal care, industrial formulations
Contact Information: Manufacturer’s information, emergency phone numbers, and address appear here
Emergency Overview: Non-volatile liquid or solid, low odor, often pale to amber color

Hazard Identification

Physical State: Liquid, viscous liquid, or sometimes solid depending on ethoxylation
Color: Colorless to pale yellow
Signal Word: None required under GHS
Hazard Statements: Causes mild skin irritation, may cause eye irritation; not classified as hazardous according to OSHA or GHS in most forms; minimal inhalation risks
Precautionary Statements: Avoid eye contact, prolonged skin contact; do not ingest; ensure adequate ventilation during use
Potential Health Effects: Skin – Mild, reversible irritation; Eyes – Stinging, watering, redness; Ingestion – Mild irritation, nausea; Inhalation – Not a significant route under normal conditions
Chronic Health Hazards: No evidence of chronic or cumulative toxicity in available animal studies
Target Organs: No systemic toxicity established from short or long-term exposures

Composition / Information on Ingredients

Chemical Name: Alkyl Ethoxy Polyglycosides
Content: 50–100% by weight
Impurities: Small percentages of unreacted alcohols, fatty alcohols (<2%), water (<10%)
Other ingredients: Trace contaminants such as residual catalysts and byproducts from manufacturing, typically less than 1%
Hazardous Components: Not classified as hazardous, but trace impurities may cause sensitization in susceptible individuals
Additives: Product stabilizers and preservatives appear in some commercial formulations at low concentrations; consult specific MSDS for detailed breakdown

First Aid Measures

Eye Contact: Flush with plenty of lukewarm water for at least fifteen minutes, holding eyelids open, remove contact lenses if present, continue rinsing, seek medical advice if irritation persists
Skin Contact: Remove contaminated clothing, wash skin thoroughly with mild soap and water, apply moisturizing lotion if irritation occurs, consult physician if symptoms worsen
Inhalation: Move exposed person to fresh air, keep at rest, consult a physician if adverse symptoms continue, rare due to low volatility
Ingestion: Rinse mouth with water, do not induce vomiting, seek medical attention if large quantities are swallowed or symptoms appear
Notes for Physicians: No specific antidote, treat symptomatically, provide supportive care

Fire-Fighting Measures

Suitable Extinguishing Media: Use water spray, dry chemical powder, foam or carbon dioxide
Unsuitable Media: Strong water jets may spread liquid
Hazards from Combustion: May release carbon monoxide, carbon dioxide, small amounts of aldehydes, or other organics when burned at high temperature
Special Protective Equipment: Firefighters should use self-contained breathing apparatus and full protective gear
Unusual Fire Hazards: Product itself is not easily flammable, but containers may rupture due to buildup of pressure under high heat
Advice for Firefighters: Keep containers cool by spraying with water, prevent run-off from contaminating waterways

Accidental Release Measures

Personal Precautions: Wear protective gloves, goggles, and suitable clothing; avoid walking through spilled product
Environmental Precautions: Prevent entry into drains, sewers, and surface water
Cleanup Methods: Absorb small liquid spills with inert material (sand, earth, vermiculite), scoop up material, wash spill area with plenty of water; collect solids for disposal in appropriate waste containers
Prevention of Secondary Hazards: Remove all sources of ignition if large quantities are involved, ventilate area to avoid accumulation of vapors
Disposal Methods: Place recovered material in labeled, sealed containers for proper disposal according to local regulations

Handling and Storage

Handling: Use with adequate ventilation, avoid splashing or spilling, avoid contact with skin and eyes; do not eat, drink, or smoke while handling
Storage Conditions: Store in tightly closed containers in a dry, cool, ventilated area, away from direct sunlight and incompatible substances
Incompatibilities: Strong acids, strong oxidizing agents
Specific Requirements: Protect from freezing or excessive heat; avoid storing near food, feed, or potable water supplies
Hygiene Practices: Wash hands, forearms, and face after use; launder contaminated clothing before reuse

Exposure Controls and Personal Protection

Occupational Exposure Limits: No established exposure limits for this product in the workplace
Engineering Controls: Provide adequate general and local exhaust ventilation where large quantities are handled
Personal Protective Equipment: Safety glasses with side-shields or splash goggles, chemical-resistant gloves (nitrile or PVC recommended); protective clothing for extensive handling or risk of splashes
Hygiene Measures: After using product, wash hands and face thoroughly before eating, drinking, or smoking
Respiratory Protection: If ventilation is insufficient or vapor formation likely, use NIOSH/MSHA-approved organic vapor respirator

Physical and Chemical Properties

Appearance: Clear or slightly hazy liquid, sometimes a waxy or granular solid
Color: Pale yellow to colorless
Odor: Mild, sweet or soapy, characteristic
Odor Threshold: Not established
pH: 6 to 11 (10% aqueous solution)
Melting Point/Freezing Point: Variable, often below 0°C for liquids
Initial Boiling Point: Above 100°C
Flash Point: More than 100°C closed cup (not easily flammable)
Evaporation Rate: Slow
Flammability: Not classified as flammable
Vapor Pressure: Negligible at room temperature
Relative Density: 1.05–1.20 g/cm³ at 25°C
Solubility: Soluble in water, miscible with polar solvents
Partition Coefficient (n-octanol/water): Low (<1); product favors water phase
Auto-Ignition Temperature: Above 250°C
Viscosity: Varies, generally high for concentrated liquids
Decomposition Temperature: Over 200°C, with smoke and possible toxic products

Stability and Reactivity

Chemical Stability: Stable under normal temperatures and recommended storage conditions
Reactivity: Unreactive under normal conditions
Conditions to Avoid: Prolonged exposure to heat, freezing, direct sunlight
Incompatible Materials: Strong oxidizers (e.g., hydrogen peroxide), strong acids, strong bases
Hazardous Decomposition Products: Thermal decomposition may release carbon oxides and trace organic compounds
Hazardous Polymerization: Not expected to occur

Toxicological Information

Acute Toxicity: High LD50 (>5,000 mg/kg oral, rat); low toxicity from short-term exposure
Skin Corrosion/Irritation: Mild, reversible irritation in rabbits and humans reported after repeated skin contact
Serious Eye Damage/Irritation: Moderate irritation to eyes possible; stinging and tearing after exposure
Respiratory Sensitization: Low volatility makes inhalation risk negligible
Skin Sensitization: Not considered a sensitizer in standard animal studies
Germ Cell Mutagenicity: No evidence of mutagenic effects noted in testing
Carcinogenicity: Not listed as a carcinogen by IARC, NTP, OSHA
Reproductive Toxicity: Animal studies indicate no birth defects or reproductive harm
STOT - Single/Repeated Exposure: No evidence of specific target organ toxicity in animal tests or lab use

Ecological Information

Ecotoxicity: Moderately toxic to aquatic life in high concentrations; LC50 (fish, 96h) – typically 5–50 mg/L
Persistence and Degradability: Readily biodegradable; tests show >80% degradation in 28 days
Bioaccumulative Potential: Low potential; log Kow <1 indicates product will not build up in living organisms
Mobility in Soil: High mobility in water, may leach through soil rapidly; risk to aquatic organisms comes from direct release to water
Other Adverse Effects: Not expected to contribute to ozone depletion, photochemical smog, or soil toxicity
Environmental Precautions: Avoid unnecessary discharge to surface water, sewers, or environment; treat rinsate as chemical waste

Disposal Considerations

Disposal Methods: Dispose of in accordance with national, regional, and local regulations; chemical residues should not be emptied into drains
Waste Treatment: Incinerate in controlled facility wherever possible, or landfill if permitted; avoid direct discharge to rivers or lakes
Container Disposal: Triple rinse container, offer for recycling or puncture and dispose of as solid municipal waste if legal
Precautions: Wear suitable personal protective equipment during waste handling, prevent spread of contaminated rinsate

Transport Information

UN Number: Not regulated as dangerous goods
Transport Hazard Class: Non-hazardous
Packing Group: Not applicable
Marine Pollutant: Not listed as a marine pollutant
Special Precautions for User: Transport in upright, tightly sealed containers, avoid rough handling that could result in leakage
DOT Classification (US): Not regulated
IATA / IMDG: Not classified as hazardous or restricted air/sea cargo

Regulatory Information

OSHA Regulatory Status: Not classified as hazardous under U.S. OSHA Hazard Communication Standard
TSCA Inventory (US): All ingredients listed or exempt
DSL/NDSL (Canada): All components appear on Domestic Substances List
EU Regulations: Not classified as hazardous under EU CLP Regulation 1272/2008
SARA Title III Sections 302/313: Not subject to reporting
California Proposition 65: Not listed
WHMIS (Canada): Not controlled
Other International Requirements: Complies with key chemical safety standards in Asia, Australia, and Latin America